Two different hues can have very similar values even when they look very different in color.
For instance, a yellow with a value of 5 is the same value as a level 5 purple even though we tend to think of purple as a darker color than yellow. In grayscale, same value colors look like the same gray.
For more on value, see contrast.
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*Copic Markers notoriously run opposite. The last number on the marker cap indicates color value. In Copic, high last numbers are dark while low last numbers are light.